- Physical Chemistry Of Metals Darken And Gurry Pdf Download
- Physical Chemistry Of Metals Darken And Gurry Pdf Software
Abstract
The activity of FeTiO3 in the binary ilmenitepyrophanite (FeTiO3-MnTiO3) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO3=2 Fe+2 TiO2+O2 in T-μO2 space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, WilmFe-Mn, of 2.2±0.3 kJ g-atom−1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives WgtFe-Mn=1.2±0.5 kJ g-atom−1 for the almandine-spessartine (Fe3Al2Si3O12-Mn3Al2Si3O12) solid solution.
Additional Physical Format: Online version: Darken, Lawrence S. (Lawrence Stamper), 1909-Physical chemistry of metals. New York, McGraw-Hill, 1953 (OCoLC)573433427: Document Type: Book: All Authors / Contributors: Lawrence S Darken; Robert W Gurry.
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- Physical Chemistry Of Metals Darken And Gurry Pdf Download
- Physical Chemistry Of Metals Darken And Gurry Pdf Software
Abstract
The activity of FeTiO3 in the binary ilmenitepyrophanite (FeTiO3-MnTiO3) solid solution has been determined for the temperature range 1050–1300 K by displacement of the reaction: 2 FeTiO3=2 Fe+2 TiO2+O2 in T-μO2 space, using an electrochemical technique with calcia- and yttria-stabilized zirconia solid electrolytes. The activities show small positive deviations from ideality, which, although the data are unusually precise, may be perfectly described by the simple regular solution model, with an interaction parameter, WilmFe-Mn, of 2.2±0.3 kJ g-atom−1, which is independent of temperature. This value, together with the experimental data on the partitioning of Fe and Mn between ilmenite and garnet (Pownceby et al. 1987), gives WgtFe-Mn=1.2±0.5 kJ g-atom−1 for the almandine-spessartine (Fe3Al2Si3O12-Mn3Al2Si3O12) solid solution.
Additional Physical Format: Online version: Darken, Lawrence S. (Lawrence Stamper), 1909-Physical chemistry of metals. New York, McGraw-Hill, 1953 (OCoLC)573433427: Document Type: Book: All Authors / Contributors: Lawrence S Darken; Robert W Gurry.
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Physical chemistry of metals by Darken. 1909-; Gurry, Robert W. (Robert Wilton) Publication date. 14 day loan required to access EPUB and PDF files. 1) Physical Chemistry of Metals-Lawrence S, Darken and Robert W. Gurry; 2) Thermodynamics of Solids-Richard A. 3) Stoichiometric and Thermodynamics of Metallurgical Processes- Y.K.Rao. 4) Chemical Kinetics-Keith J. Pe design next software, free download. 5) Metallurgical Thermodynamics- R.
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